Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality.

نویسندگان

  • Yoko Nakano
  • Fumiko Ichiyanagi
  • Masanobu Naito
  • Yonggang Yang
  • Michiya Fujiki
چکیده

We observed the emergence and inversion of chiroptical handedness in three chiroptically silent dialkylpolysilanes during aggregation in limonene-methanol-THF tersolvents.

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عنوان ژورنال:
  • Chemical communications

دوره 48 53  شماره 

صفحات  -

تاریخ انتشار 2012